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• W2008605854 abstract "The semi-empirical spectrophotometric (SESp) method, for the indirect determination of ion exchange constants (KXBr) of ion exchange processes occurring between counterions (X– and Br–) at the cationic micellar surface, is described in this article. The method uses an anionic spectrophotometric probe molecule, N-(2-methoxyphenyl)phthalamate ion (1–), which measures the effects of varying concentrations of inert inorganic or organic salt (NavX, v = 1, 2) on absorbance, (Aob) at 310 nm, of samples containing constant concentrations of 1–, NaOH and cationic micelles. The observed data fit satisfactorily to an empirical equation which gives the values of two empirical constants. These empirical constants lead to the determination of KXBr (= KX/KBr with KX and KBr representing cationic micellar binding constants of counterions X and Br–). This method gives values of KXBr for both moderately hydrophobic and hydrophilic X–. The values of KXBr, obtained by using this method, are comparable with the corresponding values of KXBr, obtained by the use of semi-empirical kinetic (SEK) method, for different moderately hydrophobic X. The values of KXBr for X = Cl– and 2,6-Cl2C6H3CO2–, obtained by the use of SESp and SEK methods, are similar to those obtained by the use of other different conventional methods." @default.
• W2008605854 created "2016-06-24" @default.
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• W2008605854 date "2013-01-01" @default.
• W2008605854 modified "2023-10-18" @default.
• W2008605854 title "A Semi-Empirical Spectrophotometric (SESp) Method for the Indirect Determination of the Ratio of Cationic Micellar Binding Constants of Counterions X^|^ndash; and Br^|^ndash; (KX/KBr)" @default.
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• W2008605854 doi "https://doi.org/10.5650/jos.62.695" @default.
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