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• W2008659244 abstract "The title radicals were generated by thermal decomposition of (E,E)-meso- and (E,E)-(±)-5,6-di-tert-butyl-2,2,9,9-tetramethyl-3,7-decadiene (4a, b), (E)-5-(1,1-dimethylethyl)-2,2,6-trimethyl-6-phenyl-3-heptene (6), and (E)-5-(diphenyl-methyl)-2,2,6,6-tetramethyl-3-heptene (7). The activation parameters of these reactions were calculated from the rate constants which were followed over a 40°C temperature range. The enthalpies of formation of 4a, b were determined from the enthalpies of combustion and enthalpies of vaporization, those of 6 and 7 by MM2 calculation. From these data and their comparison with those of comparable saturated hydrocarbons of similar strain the radical stabilization enthalpy of the title radical RSE = 11.4 ± 1.5 kcal/mol was determined, which is in good agreement with results obtained from other model compounds (12.6 kcal/mol) previously." @default.
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• W2008659244 date "1995-03-01" @default.
• W2008659244 modified "2023-10-14" @default.
• W2008659244 title "Thermolabile hydrocarbons, 34.. Kinetics of the generation of 1,3-di-tert-butylallyl radicals by thermal CC bond cleavage reactions" @default.
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• W2008659244 doi "https://doi.org/10.1002/jlac.199519950371" @default.
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