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• W2008662212 abstract "The stereoselective synthesis of (2S,3S,7S)-3,7-dimethylpentadec-2-yl acetate (2) and propionate (3) was accomplished by utilizing the cheap and easily available chiron (R)-4-methyl-δ-valerolactone (4). The key steps were chelation-controlled addition of Gilmann reagent to chiral β-alkoxy aldehyde 12 and the Cu(I)-catalyzed coupling of Grignard reagent with bromoester 5 in the presence of NMP." @default.
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• W2008662212 date "2007-10-01" @default.
• W2008662212 modified "2023-10-14" @default.
• W2008662212 title "Stereoselective synthesis of (2S,3S,7S)-3,7-dimethylpentadec-2-yl acetate and propionate, the sex pheromones of pine sawflies" @default.
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• W2008662212 doi "https://doi.org/10.1016/j.tetlet.2007.06.123" @default.
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