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- W2008666275 abstract "New heteronuclear complexes containing oxorhenium(V), Cu(II), Ni(II), Fe(III), UO2(VI) and Th(IV) ions were prepared by the reaction of the complex ligand, [ReO(H4L)Cl]Cl2, where H4L = 8,17-dimethyl-6,15-dioxo-5,7,14,16-tetrahydrodibenzo[a,h][14]annulene-2,11-dicarboxylic acid, with the previous transition and actinide salts. Three heteronuclear Cu(II) complexes were isolated depending on the ratio of [ReO(H4L)Cl]Cl2 : Cu(II) ion. When the ratios were 1 : 0.5, 1 : 1 and 1 : 2, the heteronuclear complexes {[ReO(H3L)Cl]2CuCl2(OH2)2}SO4 · H2O (I), [ReO(H3L)Cl2Cu(OH2)2(SO4)] (II) and {ReO(H2L)Cl[Cu(OH2)3 SO4]2} (III) were obtained, respectively. Heteronuclear complexes of the other metal cations were obtained by mixing [ReO(H4L)Cl]Cl2 with the metal salt in the ratio 1 : 1 to obtain the heteronuclear complexes [ReO(H3L)Cl2Ni(OH2)2](NO3)2 (IV), [ReO(H3L)Cl3Fe(OH2)3](NO3)2 (V), [ReO(H3L)ClUO2(NO3)2 (OH2)]Cl (VI) and [ReO(H3L)Cl3Th(NO3)2(OH2)]NO3 · 2H2O (VII). The complex ligand coordinates with the heterometal ..." @default.
- W2008666275 created "2016-06-24" @default.
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- W2008666275 date "2004-02-15" @default.
- W2008666275 modified "2023-09-25" @default.
- W2008666275 title "Heterobinuclear and Heterotrinuclear complexes of Oxorhenium(V) with Cu(II), Ni(II), Fe(III), UO2(VI) and Th(IV) in the solid state" @default.
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- W2008666275 doi "https://doi.org/10.1080/00958970410001671101" @default.
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