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- W2008680337 abstract "The behaviour of α,β-dioxopropionic acid derivatives of the type RCOCOCOX (R = phenyl, p-substituted phenyls, CF3, mesityl; X = OC2H5, NH2) was investigated under benzilic acid rearrangement conditions. Nearly all compounds were cleaved by alkali to give the corresponding acids RCOOH and glyoxylic acid. Only the sterically hindered ethyl β-mesityl-α,β-dioxopropionate underwent rearrangement (after hydrolysis of the ester group); it was shown by 14C-labelling that the carboxylate group migrates to the β-carbonyl group." @default.
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- W2008680337 date "1974-11-06" @default.
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- W2008680337 title "Umlagerung und Spaltung von α, β-Dioxopropionsäureestern in alkalischem Milieu. 28. Mitt. über Reduktone und Tricarbonylverbindungen [1]" @default.
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- W2008680337 doi "https://doi.org/10.1002/hlca.19740570737" @default.
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