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- W2008695744 abstract "Hydrogels based on ethoxytriethyleneglycol monomethacrylate/methyl methacrylate (T/M) copolymers were prepared by free radical polymerization at 70°C in bulk with azobisisobutyronitrile as initiator. The reactivity ratios were calculated by Fineman–Ross (FR) and Kelen–Tudos (KT) linearization methods and by the non-linear least square method suggested by Tidwell and Mortimer (TM). The reactivity ratios obtained were rT=0·17±0·03, rM=0·70±0·01 (FR method); rT=0·19±0·02, rM=0·76±0·03 (KT method) and rT=0·18; rM= 0·75 (TM method). Microstructure was obtained in terms of the distribution of T- and M-centred triads. The swelling behaviour of the hydrogels was studied by immersion of the films in water and in buffered solutions at various pH values and it was analysed by comparison with that of poly(ethoxytriethyleneglycol monomethacrylate). It was observed that not only the average copolymer composition but also the distribution of monomeric sequences play an important role in the swelling behaviour. © 1997 SCI." @default.
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- W2008695744 date "1997-06-01" @default.
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- W2008695744 title "Non-ionizable Polyacrylic Hydrogels Sensitive to pH for Biomedical Applications" @default.
- W2008695744 doi "https://doi.org/10.1002/(sici)1097-0126(199706)43:2<182::aid-pi726>3.0.co;2-d" @default.
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