FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2008725311> ?p ?o ?g. }

• W2008725311 endingPage "451" @default.
• W2008725311 startingPage "443" @default.
• W2008725311 abstract "Tantalum pentoxide (Ta2O5) is a promising material for the realization of biological interfaces because of its high dielectric constant, its high chemical stability, and its excellent passivating properties. Nevertheless, the deposition of highly organized silane SAMs to realize well-defined and tailored Ta2O5-based (bio)interfaces, has not been studied in great detail as of yet. In this work, we have investigated the formation of a highly ordered, dense monolayer of trichlorosilanes on Ta2O5 surfaces. Specifically, two different cleaning procedures for Ta2O5 were compared and (n-decyl)trichlorosilane (DTS) was used to study the effect of both cleaning methods on the silanization of Ta2O5. Both types of cleaning allowed the formation of complete and crystalline DTS monolayers on Ta2O5, in contrast with the incomplete, disordered silane layer assembled on uncleaned Ta2O5. The deposited self-assembled monolayers were studied by means of contact angle goniometry, Brewster angle FTIR, X-ray photoelectron spectroscopy, cyclic voltammetry, and ellipsometry. Infrared analysis exhibited a highly ordered DTS silane film on Ta2O5 and indicated a larger tilt angle of the alkyl chains on this substrate by comparison to DTS on SiO2. Furthermore, with use of ellipsometry and XPS, the silane film thickness on Ta2O5 was determined to be substantially smaller than that reported in the literature for DTS on SiO2, supporting the observations of an increased tilt angle (∼45°) on Ta2O5 than on SiO2 (∼10°). By means of cyclic voltammetry, the formation of a dense, essentially pinhole-free, silane film was observed on the cleaned samples. In conclusion, the fully characterized and optimized procedure for the silanization of Ta2O5 surfaces with trichlorosilanes will allow the formation of well-defined, reproducible, and controllable chemical interfaces on Ta2O5." @default.
• W2008725311 created "2016-06-24" @default.
• W2008725311 creator A5001118268 @default.
• W2008725311 creator A5004465049 @default.
• W2008725311 creator A5016861508 @default.
• W2008725311 creator A5034947768 @default.
• W2008725311 creator A5044046276 @default.
• W2008725311 creator A5087975686 @default.
• W2008725311 creator A5088001195 @default.
• W2008725311 date "2006-11-16" @default.
• W2008725311 modified "2023-10-03" @default.
• W2008725311 title "Formation of Dense Self-assembled Monolayers of (<i>n</i>-Decyl)trichlorosilanes on Ta/Ta₂O₅" @default.
• W2008725311 cites W1506823599 @default.
• W2008725311 cites W1601278949 @default.
• W2008725311 cites W1963740321 @default.
• W2008725311 cites W1963842392 @default.
• W2008725311 cites W1964074855 @default.
• W2008725311 cites W1967598238 @default.
• W2008725311 cites W1967662238 @default.
• W2008725311 cites W1969444751 @default.
• W2008725311 cites W1970073500 @default.
• W2008725311 cites W1972091231 @default.
• W2008725311 cites W1972834914 @default.
• W2008725311 cites W1981378237 @default.
• W2008725311 cites W1983931502 @default.
• W2008725311 cites W1987815161 @default.
• W2008725311 cites W1989048448 @default.
• W2008725311 cites W1990000198 @default.
• W2008725311 cites W1990146884 @default.
• W2008725311 cites W1990212751 @default.
• W2008725311 cites W1992123007 @default.
• W2008725311 cites W2001558690 @default.
• W2008725311 cites W2006923533 @default.
• W2008725311 cites W2013685121 @default.
• W2008725311 cites W2017094523 @default.
• W2008725311 cites W2020018559 @default.
• W2008725311 cites W2024885413 @default.
• W2008725311 cites W2025977329 @default.
• W2008725311 cites W2035300414 @default.
• W2008725311 cites W2036092043 @default.
• W2008725311 cites W2039227080 @default.
• W2008725311 cites W2040484994 @default.
• W2008725311 cites W2041380863 @default.
• W2008725311 cites W2045691265 @default.
• W2008725311 cites W2046142803 @default.
• W2008725311 cites W2046587347 @default.
• W2008725311 cites W2049667872 @default.
• W2008725311 cites W2051489942 @default.
• W2008725311 cites W2054658719 @default.
• W2008725311 cites W2056648038 @default.
• W2008725311 cites W2057448348 @default.
• W2008725311 cites W2066416729 @default.
• W2008725311 cites W2073628878 @default.
• W2008725311 cites W2085999853 @default.
• W2008725311 cites W2088556077 @default.
• W2008725311 cites W2088624623 @default.
• W2008725311 cites W2092686831 @default.
• W2008725311 cites W2094752432 @default.
• W2008725311 cites W2102498367 @default.
• W2008725311 cites W2120469859 @default.
• W2008725311 cites W2134432028 @default.
• W2008725311 cites W2134819724 @default.
• W2008725311 cites W2143997675 @default.
• W2008725311 cites W2144768486 @default.
• W2008725311 cites W2146076760 @default.
• W2008725311 cites W2152835519 @default.
• W2008725311 cites W4238505678 @default.
• W2008725311 doi "https://doi.org/10.1021/la061951e" @default.
• W2008725311 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17209592" @default.
• W2008725311 hasPublicationYear "2006" @default.
• W2008725311 type Work @default.
• W2008725311 sameAs 2008725311 @default.
• W2008725311 citedByCount "36" @default.
• W2008725311 countsByYear W20087253112012 @default.
• W2008725311 countsByYear W20087253112013 @default.
• W2008725311 countsByYear W20087253112014 @default.
• W2008725311 countsByYear W20087253112015 @default.
• W2008725311 countsByYear W20087253112016 @default.
• W2008725311 countsByYear W20087253112017 @default.
• W2008725311 countsByYear W20087253112019 @default.
• W2008725311 countsByYear W20087253112020 @default.
• W2008725311 countsByYear W20087253112021 @default.
• W2008725311 crossrefType "journal-article" @default.
• W2008725311 hasAuthorship W2008725311A5001118268 @default.
• W2008725311 hasAuthorship W2008725311A5004465049 @default.
• W2008725311 hasAuthorship W2008725311A5016861508 @default.
• W2008725311 hasAuthorship W2008725311A5034947768 @default.
• W2008725311 hasAuthorship W2008725311A5044046276 @default.
• W2008725311 hasAuthorship W2008725311A5087975686 @default.
• W2008725311 hasAuthorship W2008725311A5088001195 @default.
• W2008725311 hasConcept C113196181 @default.
• W2008725311 hasConcept C120665830 @default.
• W2008725311 hasConcept C121332964 @default.
• W2008725311 hasConcept C127413603 @default.
• W2008725311 hasConcept C147789679 @default.
• W2008725311 hasConcept C159985019 @default.
• W2008725311 hasConcept C160892712 @default.
• W2008725311 hasConcept C171250308 @default.

• next