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- W2008730007 abstract "Modulation of steric interactions remote from the active sites within a series of dinuclear bis-propagators derived from racemic 2-4 was used to attenuate the rate of reversible chain transfer between active transition-metal centers and excess equivalents of inactive main-group-metal alkyl species relative to chain growth propagation, as a strategy for achieving the stereoselective living coordinative chain transfer polymerization of propene to provide isotactic stereoblock polypropene. Under identical conditions, the corresponding mononuclear propagator derived from racemic 1 produced only atactic polypropene." @default.
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- W2008730007 date "2013-01-29" @default.
- W2008730007 modified "2023-09-26" @default.
- W2008730007 title "Dinuclear Bis-Propagators for the Stereoselective Living Coordinative Chain Transfer Polymerization of Propene" @default.
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- W2008730007 doi "https://doi.org/10.1021/ja312463f" @default.
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