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- W2008755036 abstract "The Mn2+ EPR spectra in glasses are treated by a computer simulation technique taking into account the distributions of the fine structure parameters D and E resulting from random variations in local environments of the paramagnetic ion. Simulated spectra are displayed for different values of the D0E0 ratio and for different values of the parameter distributions, ΔD and ΔE. The good agreement observed between the simulated and experimental spectra for phosphate and silicate glasses permits determination of the spin-Hamiltonian parameters and their distributions. It is concluded that Mn2+ ions with g = 2.0 in glasses form a distinct site characterized by the following spin-Hamiltonian parameters: |D0|gβ = 220 ± 20 G, |E0|gβ = 70 ± 15 G, A/gβ = −93 ± 1 G (for the phosphate glass) and A/gβ = − 87 ± 1 G (for the silicate glass). The fine structure parameters have considerable distributions, ΔD/gβ = 80 ± 20 G, ΔE/gβ = 30 ± 10 G, due to the structural disorder of the glasses." @default.
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- W2008755036 title "Simulation of EPR spectra of Mn2+ in glasses" @default.
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- W2008755036 doi "https://doi.org/10.1016/0022-2364(80)90227-9" @default.
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