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• W2008766641 abstract "The powder synchrotron X-ray diffraction technique was used to study the temperature evolution of the structural properties of the mixed valence rare earth fulleride, Yb2.75C60, in the temperature range 5−295 K. The large lattice expansion (negative thermal expansion) on cooling below 60 K provides an unambiguous signature of a temperature-induced valence transition of the Yb atoms. The transformation is of electronic origin and is driven by the coupling of the Yb 4f band and the t1u band of C60. It is analogous to that observed at lower temperatures in Sm2.75C60, but it is absent when the electronically active 4f sublattice is missing in the related alkaline earth fulleride, Ca2.75C60." @default.
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• W2008766641 date "2005-08-01" @default.
• W2008766641 modified "2023-09-30" @default.
• W2008766641 title "Negative Thermal Expansion in the Mixed Valence Ytterbium Fulleride, Yb_2.75C₆₀" @default.
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• W2008766641 doi "https://doi.org/10.1021/cm051341k" @default.
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