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• W2008768672 abstract "New TICT (Twist Internal Charge Transfer) molecules are reported: aniline and N,N-dialkylanilines. The twist of an amino group around the C-N bond is even in the ground state [4] contrary to TICT molecules previously reported (N,N-dialkylaninile para derivatives) [1,2,3]. An intermolecular interaction study confirms an important cage effect at low temperature. CNDO/M spectroscopic calculations are consistent with absorption and emission experimental results [4,5]. The twist implies: (i) diminishing of oscillator strength, coherent with absorption; (ii) the CT character of the S2 state which explains the emission anomaly (IPh/IFl depending on excitation wavelength); (iii) polarization different and consistent with phosphorescence polarization results obtained with different excitations." @default.
• W2008768672 created "2016-06-24" @default.
• W2008768672 creator A5073581594 @default.
• W2008768672 date "1984-01-01" @default.
• W2008768672 modified "2023-09-27" @default.
• W2008768672 title "Confirmation of a cage effect at low temperature with aniline and N,N-dimethylaniline" @default.
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• W2008768672 doi "https://doi.org/10.1016/s0022-2313(84)90101-7" @default.
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