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• W2008773818 startingPage "8224" @default.
• W2008773818 abstract "The temperature and pressure dependences of the dielectric constants have been measured on the mixed-stack organic charge-transfer crystal, tetrathiafulvalene-p-chloranil, in a frequency range from 100 Hz to 10 MHz. The dielectric response increases remarkably with decreasing temperature down to ${mathit{T}}_{mathit{c}}$=81 K, where the neutral-to-ionic (NI) phase transition occurs. On the other hand, with applied pressure at room temperature, the change in the dielectric response is less remarkable, whereas the dc conductivity ${mathrm{ensuremath{sigma}}}_{mathrm{dc}}$ increases considerably. Such dynamical responses are explained by a Debye-type relaxation model. The strength of the dielectric response is closely correlated with both the relaxation time ensuremath{tau} and ${mathrm{ensuremath{sigma}}}_{mathrm{dc}}$. These anomalous dielectric responses are attributed to the dynamics of the NI domain-wall pairs and ionic domains in the neutral lattice." @default.
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• W2008773818 date "1991-04-01" @default.
• W2008773818 modified "2023-09-30" @default.
• W2008773818 title "Anomalous dielectric response in tetrathiafulvalene-<i>p</i>-chloranil as observed in temperature- and pressure-induced neutral-to-ionic phase transition" @default.
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• W2008773818 doi "https://doi.org/10.1103/physrevb.43.8224" @default.
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