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- W2008777003 abstract "The observable cyclodecyl cation is established as having a 1,5-μ-hydrido-bridged structure and most probably exists as a mixture of conformational isomers. This solution carbocation is unique in organic chemistry in that it evolves molecular H2 at temperatures below -100°C to give the 9-decalyl cation. The mechanism of this reaction is postulated to involve a pentacoordinated carbocation intermediate or transition state with a structure identical to what one would get by protonating the bridgehead C-H bond of decalin. Since conversion of decalin to the decalyl cation in superacids is not accompanied by significant H2 production, the mechanism of these two reactions must be different, and in the latter case could not involve a protonated pentacoordinate carbocation intermediate, as has been postulated." @default.
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- W2008777003 date "1986-01-01" @default.
- W2008777003 modified "2023-09-25" @default.
- W2008777003 title "The characterization of and the evolution of molecular hydrogen by the μ-hydrido-bridged cyclodecyl cation. Relevance to the question of hydrocarbon protonation by superacids" @default.
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- W2008777003 doi "https://doi.org/10.1016/s0040-4020(01)87510-4" @default.
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