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• W2008898981 abstract "Photoelectron spectra of (NO)n− (1≤n≤7) were recorded at a photon energy of 4.66 eV, and the vertical detachment energies (VDEs) were determined as a function of the cluster size. The VDE shows an abrupt increase from 2.93±0.05 eV for n=2 to 3.70±0.02 eV for n=3. This large VDE shift is attributed to the formation of the N3O3− molecular anion, which acts as a core in the larger clusters; hence, the (NO)n− clusters with n≥3 are well described as N3O3−·(NO)n−3. Ab initio calculations at the MP2/6-31+G* level predict that the N3O3− molecular anion occurs with isomeric forms having either normal or branched chain configuration." @default.
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• W2008898981 date "1998-10-01" @default.
• W2008898981 modified "2023-10-02" @default.
• W2008898981 title "Formation of N3O3− anion in (NO)−: photoelectron spectroscopy and ab initio calculations" @default.
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• W2008898981 doi "https://doi.org/10.1016/s0009-2614(98)01002-1" @default.
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