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- W2008933029 abstract "Large ${mathrm{Li}}_{3}{mathrm{ThF}}_{7}$ single crystals have been obtained by the Czochralski technique. Calorimetric and dielectric investigations over a large temperature range (100--800 K) demonstrate the existence of two additional first-order phase transitions (at about 281 and 467 K), beside the known tetragonal-to-orthorhombic one, found at 368 K, 27 K higher than the reported temperature. The knowledge of the structures of these additional phases, besides the phase transition mechanisms, can help to prevent the multiple microcracks which develop in the sample after crystal growth and limit its technological applications. Conductivity measurements show also the high anisotropic character of the ${mathrm{Li}}^{+}$ ion's mobility." @default.
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- W2008933029 date "1997-10-01" @default.
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- W2008933029 title "Phase transition sequence ofLi3ThF7crystals" @default.
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- W2008933029 doi "https://doi.org/10.1103/physrevb.56.7755" @default.
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