Matches in SemOpenAlex for { <https://semopenalex.org/work/W2008936013> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2008936013 endingPage "5602" @default.
- W2008936013 startingPage "5599" @default.
- W2008936013 abstract "1,1-Difluoro-2,2-bis(dimethylamino)ethene undergoes a [2 + 2] cycloaddition with ethyl propiolate at −25 °C [ΔH⧧ = 4.2 (±0.4) kcal/mol and ΔS⧧ = −56.7 (±0.9) cal/mol·K], and the cyclobutene product undergoes electrocyclic ring opening at +15 °C [ΔH⧧ = 18.5 (±0.6) kcal/mol and ΔS⧧ = −9.7 (±1.0) cal/mol·K]. The resultant diene undergoes Diels−Alder reactions with electron-deficient dienophiles to give aromatic products. A complementary computational study addresses the issue of the [2 + 2] cycloaddition mechanism." @default.
- W2008936013 created "2016-06-24" @default.
- W2008936013 creator A5019944886 @default.
- W2008936013 creator A5031099164 @default.
- W2008936013 creator A5081853872 @default.
- W2008936013 date "1999-07-01" @default.
- W2008936013 modified "2023-09-23" @default.
- W2008936013 title "Synthetic and Mechanistic Aspects of the Reaction of 1,1-Difluoro-2,2-bis(dimethylamino)ethene with Ethyl Propiolate" @default.
- W2008936013 cites W135867663 @default.
- W2008936013 cites W1993013485 @default.
- W2008936013 cites W2032717508 @default.
- W2008936013 cites W2044742296 @default.
- W2008936013 cites W2047744185 @default.
- W2008936013 cites W2079473982 @default.
- W2008936013 cites W2094619287 @default.
- W2008936013 cites W2094642658 @default.
- W2008936013 cites W2102964261 @default.
- W2008936013 cites W2151334055 @default.
- W2008936013 cites W2172261176 @default.
- W2008936013 cites W2316410310 @default.
- W2008936013 cites W2951533447 @default.
- W2008936013 cites W3004465863 @default.
- W2008936013 cites W4242582203 @default.
- W2008936013 cites W2314445765 @default.
- W2008936013 doi "https://doi.org/10.1021/jo990609m" @default.
- W2008936013 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11674628" @default.
- W2008936013 hasPublicationYear "1999" @default.
- W2008936013 type Work @default.
- W2008936013 sameAs 2008936013 @default.
- W2008936013 citedByCount "7" @default.
- W2008936013 countsByYear W20089360132018 @default.
- W2008936013 countsByYear W20089360132020 @default.
- W2008936013 countsByYear W20089360132021 @default.
- W2008936013 crossrefType "journal-article" @default.
- W2008936013 hasAuthorship W2008936013A5019944886 @default.
- W2008936013 hasAuthorship W2008936013A5031099164 @default.
- W2008936013 hasAuthorship W2008936013A5081853872 @default.
- W2008936013 hasConcept C155647269 @default.
- W2008936013 hasConcept C161790260 @default.
- W2008936013 hasConcept C176933379 @default.
- W2008936013 hasConcept C178790620 @default.
- W2008936013 hasConcept C185592680 @default.
- W2008936013 hasConcept C24961977 @default.
- W2008936013 hasConcept C2775855009 @default.
- W2008936013 hasConcept C2776011334 @default.
- W2008936013 hasConcept C2778733088 @default.
- W2008936013 hasConcept C2779664164 @default.
- W2008936013 hasConcept C2780378348 @default.
- W2008936013 hasConcept C65024703 @default.
- W2008936013 hasConcept C71240020 @default.
- W2008936013 hasConceptScore W2008936013C155647269 @default.
- W2008936013 hasConceptScore W2008936013C161790260 @default.
- W2008936013 hasConceptScore W2008936013C176933379 @default.
- W2008936013 hasConceptScore W2008936013C178790620 @default.
- W2008936013 hasConceptScore W2008936013C185592680 @default.
- W2008936013 hasConceptScore W2008936013C24961977 @default.
- W2008936013 hasConceptScore W2008936013C2775855009 @default.
- W2008936013 hasConceptScore W2008936013C2776011334 @default.
- W2008936013 hasConceptScore W2008936013C2778733088 @default.
- W2008936013 hasConceptScore W2008936013C2779664164 @default.
- W2008936013 hasConceptScore W2008936013C2780378348 @default.
- W2008936013 hasConceptScore W2008936013C65024703 @default.
- W2008936013 hasConceptScore W2008936013C71240020 @default.
- W2008936013 hasIssue "15" @default.
- W2008936013 hasLocation W20089360131 @default.
- W2008936013 hasLocation W20089360132 @default.
- W2008936013 hasOpenAccess W2008936013 @default.
- W2008936013 hasPrimaryLocation W20089360131 @default.
- W2008936013 hasRelatedWork W1546119241 @default.
- W2008936013 hasRelatedWork W2005912963 @default.
- W2008936013 hasRelatedWork W2008936013 @default.
- W2008936013 hasRelatedWork W2024566899 @default.
- W2008936013 hasRelatedWork W2031034006 @default.
- W2008936013 hasRelatedWork W2949489524 @default.
- W2008936013 hasRelatedWork W2949749362 @default.
- W2008936013 hasRelatedWork W2949956248 @default.
- W2008936013 hasRelatedWork W2950375487 @default.
- W2008936013 hasRelatedWork W4311608953 @default.
- W2008936013 hasVolume "64" @default.
- W2008936013 isParatext "false" @default.
- W2008936013 isRetracted "false" @default.
- W2008936013 magId "2008936013" @default.
- W2008936013 workType "article" @default.