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- W2008952823 abstract "We report a novel trans-silylvinylation of internal alkynes catalyzed by RuHCl(CO)(PCy3)2. This method represents a highly regio- and stereoselective synthesis of functionalized dienes by means of an efficient tandem alkyne trans-silylruthenation, followed by an addition to acrylates. The products are further transformed by Pd-catalyzed cross couplings and carbonylations to afford dienes with significantly increased molecular complexity." @default.
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- W2008952823 date "2013-01-01" @default.
- W2008952823 modified "2023-10-16" @default.
- W2008952823 title "Regio- and stereoselective trans-silylvinylation of internal alkynes catalyzed by RuHCl(CO)(PCy3)2" @default.
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- W2008952823 doi "https://doi.org/10.1039/c3sc22002h" @default.
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