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- W2008954803 abstract "The catalytic hydrogenation of ethylene over the non-stoichiometric calcium hydride (CaH2−δ) prepared by means of high-temperature evacuation was studied. The order of introducing gases had no effect on the rate of ethylene hydrogenation. The rate expressions for the initial stage were ν=k PH0.8–1.0 PE and ν′=k′ PH0.8–1.0 PE0 in the lower and higher pressure ranges of ethylene respectively. The amount of hydrogen bound initially to CaH2−δ and participating in the reaction was estimated from the results of the D2–CaH2−δ exchange and H2–D2 equilibration reactions. From these results, the mechanism of ethylene hydrogenation over calcium hydride and the role of the hydrogen of the hydride were discussed. The poisoning caused by water and acetylene was also studied. Furthermore, the catalytic activity of calcium hydride was compared with that of three metallic hydrides." @default.
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- W2008954803 date "1975-05-01" @default.
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- W2008954803 title "The Catalytic Hydrogenation of Ethylene over Calcium Hydride and the Role of the Hydrogen of the Hydride" @default.
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- W2008954803 doi "https://doi.org/10.1246/bcsj.48.1345" @default.
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