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- W2008994004 abstract "The first series of conformationally constrained analogues of homotaurine is reported. The partial constriction of the skeleton was realized through the insertion of a cyclopropyl ring, between the α,β- and β,γ-positions, thus affording, respectively, trans- and cis-2-aminomethylcyclopropane-1-sulfonic acids and trans- and cis-(2-aminocyclopropyl)methanesulfonic acids. The resolution of all four racemic mixtures was accomplished using HPLC system carrying the polysaccharide-based Chiralpak® IB® column as the chiral stationary phase. The coupling with an ‘Evaporative Light Scattering Detector (ELSD)’ has been particularly valuable during the chromatographic study." @default.
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- W2008994004 date "2009-10-01" @default.
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- W2008994004 title "Synthesis and chromatographic resolution of conformationally constrained analogues of homotaurine" @default.
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- W2008994004 doi "https://doi.org/10.1016/j.tet.2009.08.018" @default.
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