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- W2009007592 abstract "Abstract Polymeric [Cu(dien)Ix] (dien = diethylenetriamine) was prepared. Its electronic absorption spectrum and photoacoustic spectrum were recorded at room temperature. They were compared with each other and the results were discussed quantitatively with respect to ligand field theory (LFT) and the radical scaling wave function of a non-free copper(II) ion. The theoretical values are in agreement with the observed ones. In addition. the ESR spectra of the title complex were measured at 77k and room temperature, respectively. They were compared with each other and characterized. Therefore, the electronic structure was also investigated with its spectra behaviors and PLFT. The spectra and the theoretical analysis about the title complex suggest there is a weak interaction between the Cu-Cu. It can be interpreted with using Kahn's theory. The g (= 2.0942) is greater than 2.040, conforming to a ground state configuration with unpaired electron in the dx2−y2 orbital." @default.
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- W2009007592 date "1996-12-01" @default.
- W2009007592 modified "2023-09-27" @default.
- W2009007592 title "Spectra, Magnetic Property and Coordination Structure Study on Polymeric Copper(II) Iodo Complex of Diethylenetriamne" @default.
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- W2009007592 doi "https://doi.org/10.1080/00387019608007147" @default.
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