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- W2009011876 abstract "The formation of retained hydrocarbons or coke in the conversion of methanol and dimethylether to hydrocarbons over zeolite H-MFI was studied using ultraviolet Raman spectroscopy. Polyolefin, cyclopentadienyl species, and polyaromatic hydrocarbons have been identified among the retained hydrocarbons from the Raman spectra. The results strongly support a reaction mechanism, proposed previously, where cyclopentadienyl species are identified as a key intermediate in the formation of aromatic and polyaromatic hydrocarbons by ring expansion. The spectra also suggest that the polyaromatic hydrocarbons have a chain-like topology, similar to polycenes, rather than a two-dimensional, sheet-like topology, similar to pyrene or coronene." @default.
- W2009011876 created "2016-06-24" @default.
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- W2009011876 date "2003-01-01" @default.
- W2009011876 modified "2023-10-03" @default.
- W2009011876 title "An ultraviolet Raman spectroscopic study of coke formation in methanol to hydrocarbons conversion over zeolite H-MFI" @default.
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- W2009011876 doi "https://doi.org/10.1016/s0021-9517(02)00026-x" @default.
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