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- W2009014319 abstract "The transformation of n-hexane was carried out under hydrogen pressure, on platinum/mordenite and platinum/Y-zeolite with platinum areas ranging from 0 to 10–15 m2 g−1. For both series, as can be expected from the conventional bifunctional process, the isomerization activity is proportional to the platinum area for small platinum areas and almost independent of it for large platinum areas. However, the primary products of n-hexane and 3-methylpentane isomerization are notably different: the selectivity of platinum/Y-zeolite with a platinum area ≥0.5 m2 g−1 is typical of a bifunctional reaction with, as limiting step, the skeletal isomerization of intermediate olefins; that of platinum/mordenite, even with a platinum area equal to 15 m2 g−1, remains intermediate between those of platinum-free zeolites and large platinum area Y catalysts. These differences are clearly related to the higher activity of platinum/mordenite, to its lower hydrogenation activity as well as to diffusional limitations in the practically unidimensional porous structure of mordenite." @default.
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- W2009014319 date "1982-12-01" @default.
- W2009014319 modified "2023-10-15" @default.
- W2009014319 title "Hydroisomerization of n-hexane on platinum zeolites II. Comparison between the reaction mechanisms on platinum/Y-zeolite and on platinum/mordenite" @default.
- W2009014319 doi "https://doi.org/10.1016/0021-9517(82)90312-8" @default.
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