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- W2009014789 abstract "The rotational spectra for seven isotopomers of the OCS–OCS–C2H4 trimer have been observed with a Fourier transform microwave spectrometer. Their moments of inertia were fitted to a structure in which the plane of the ethylene is roughly parallel to a plane formed by the OCS monomers aligned with parallel dipoles. Dipole moment measurements and semi-empirical modeling confirmed this geometry. The transitions were split into doublets separated by 30–100 kHz by a tunneling motion in the complex. Isotopic studies indicated that this motion involved rotation of the ethylene in its molecular plane. The structure of the trimer is very similar to the HCCH–(OCS)2 trimer in which the dipoles of the two OCS monomers were also aligned parallel. The complex is compared with several dimers containing ethylene which also show tunneling motions." @default.
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- W2009014789 date "2002-07-01" @default.
- W2009014789 modified "2023-09-23" @default.
- W2009014789 title "Rotational spectrum and structure of the (OCS)2–C2H4 trimer: example of a polar OCS dimer" @default.
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- W2009014789 doi "https://doi.org/10.1016/s0022-2860(02)00097-2" @default.
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