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- W2009017919 abstract "Es werden die Schwingungsspektren von OSPF, S2PF, S2PF(CH3)− und S2P(CN) vermessen und gemeinsam mit O2PF und S2P(CH3) diskutiert und zugeordnet. Anhand der nach einem Näherungsverfahren berechneten Kraftkonstanten werden die Bindungsverhältnisse besprochen. Die negative Ionenladung bewirkt eine starke Erniedrigung von f PF. Die Ionenladung ist annähernd über alle beteiligten Atome verteilt. Vibration spectra and force constants of the series O2PF — S2PF — S2P(CH3). The vibrational spectra of OSPF, S2PF, S2PF(CH3) and S2P(CN) are reported and discussed with O2PF and S2P(CH3). On the basis of a simplified valence-force-field the force constants are calculated and the bonding relations are discussed. In the ions, f PF is lower than in corresponding molecules. The ionic charge is distributed over nearly all atoms of the ions." @default.
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- W2009017919 date "1972-08-01" @default.
- W2009017919 modified "2023-10-16" @default.
- W2009017919 title "Schwingungsspektren und Kraftkonstanten der �bergangsreihe O2PF2??S2PF2?? S2P(CH3)2?" @default.
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- W2009017919 doi "https://doi.org/10.1002/zaac.19723920106" @default.
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