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- W2009018464 abstract "Abstract Contrary to widely held beliefs, interaction of molecular iodine with alkyl vinyl ethers in methylene dichloride leads initially to equilibrium formation of appropriately substituted 1,2-di-iodoethanes. The reactions were studied spectrophotometrically at −40°C, to minimize polymerization, and it has been shown that with isobutyl vinyl ether (IBVE), the appropriate adduct was formed rapidly and completely when the mole ratio [ IBVE ] [ I 2 ] ⋍ 70 . Molecular iodine was shown to be an effectice catalyst for carbon-iodine bond heterolysis in 2-iodopropane and hence it is suggested that the important primary processes in iodine initiated polymerization of alkyl vinyl ethers involve the reactions" @default.
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- W2009018464 title "The mechanism of initiation of cationic polymerization of alkyl vinyl ethers by molecular iodine" @default.
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- W2009018464 doi "https://doi.org/10.1016/0032-3861(71)90057-7" @default.
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