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- W2009038852 abstract "In this lab experiment we describe an investigation of the thermodynamics of the formation of cyclodextrin inclusion complexes by using fluorescence spectroscopy. A naphthalene derivative, 4-(6-methoxy-2-naphthyl)-2 butanone (nabumetone), was used as a guest and two different cyclodextrins, β-cyclodextrin (β-CD) and hydroxypropyl β-cyclodextrin, (HP β-CD), were used as hosts. The thermodynamic parameters of the inclusion process were determined from the temperature dependence of the association constant by using the van't Hoff relation. The results show two different behaviors depending on the nature of the host molecule. These behaviors can be discussed in terms of the nature of driving forces responsible for the interaction. The experiment is designed for physical chemistry laboratory students, although it could also be used in a high-level physical pharmacy course." @default.
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- W2009038852 date "1999-03-01" @default.
- W2009038852 modified "2023-10-02" @default.
- W2009038852 title "Determination of Thermodynamic Parameters of the Cyclodextrin Inclusion Processes: An Undergraduate Physical Chemistry Lab Experiment" @default.
- W2009038852 doi "https://doi.org/10.1021/ed076p418" @default.
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