Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009046617> ?p ?o ?g. }
- W2009046617 endingPage "294" @default.
- W2009046617 startingPage "289" @default.
- W2009046617 abstract "We report the use of simple μ-oxo-bis[tetraphenylporphinatoiron(III)] ([TPPFeIII]2O) as a catalyst for the selective oxidation of cyclohexane into cyclohexanone and cylcohexanol with air. This is the first time that [TPPFeIII]2O has been used as a catalyst for the aerobic liquid phase oxidation of cyclohexane in absence of any cocatalyst or coreductants. The oxidation of cyclohexane catalyzed by a very small amount of [TPPFeIII]2O gave 90% selectivity to cyclohexanol and cyclohexanone at 12.55% yield and catalyst turnover numbers of 90,000 (based on the metal) under the conditions of 398 K and 0.6 MPa. We showed that the reaction yields and the turnover numbers of the catalyst changed with reaction temperature, pressure and the amount of catalyst. In contrast with the corresponding monoironporphyrin, chloro[tetraphenylporphinatoiron(III)] (TPPFeIIICl), the oxidation of cyclohexane catalyzed by (TPPFeIII)2O with air had higher yields and greater turnovers." @default.
- W2009046617 created "2016-06-24" @default.
- W2009046617 creator A5023363049 @default.
- W2009046617 creator A5031647041 @default.
- W2009046617 creator A5039414614 @default.
- W2009046617 creator A5051431915 @default.
- W2009046617 creator A5057055806 @default.
- W2009046617 creator A5081161994 @default.
- W2009046617 date "2003-02-01" @default.
- W2009046617 modified "2023-09-27" @default.
- W2009046617 title "Studies of simple μ-oxo-bisiron(III)porphyrin as catalyst of cyclohexane oxidation with air in absence of cocatalysts or coreductants" @default.
- W2009046617 cites W1964028555 @default.
- W2009046617 cites W1980001065 @default.
- W2009046617 cites W1983791889 @default.
- W2009046617 cites W1992939879 @default.
- W2009046617 cites W2004136906 @default.
- W2009046617 cites W2007517537 @default.
- W2009046617 cites W2012350335 @default.
- W2009046617 cites W2021078056 @default.
- W2009046617 cites W2023398515 @default.
- W2009046617 cites W2026089375 @default.
- W2009046617 cites W2027481658 @default.
- W2009046617 cites W2030573555 @default.
- W2009046617 cites W2031299297 @default.
- W2009046617 cites W2032057821 @default.
- W2009046617 cites W2036074372 @default.
- W2009046617 cites W2046246427 @default.
- W2009046617 cites W2051849766 @default.
- W2009046617 cites W2056522495 @default.
- W2009046617 cites W2058737804 @default.
- W2009046617 cites W2066738819 @default.
- W2009046617 cites W2072142578 @default.
- W2009046617 cites W2073356400 @default.
- W2009046617 cites W2076134053 @default.
- W2009046617 cites W2078083100 @default.
- W2009046617 cites W2079028628 @default.
- W2009046617 cites W2083189423 @default.
- W2009046617 cites W2085175356 @default.
- W2009046617 cites W2085585038 @default.
- W2009046617 cites W2090129581 @default.
- W2009046617 cites W2091115509 @default.
- W2009046617 cites W2095325222 @default.
- W2009046617 cites W2113305715 @default.
- W2009046617 cites W2130134567 @default.
- W2009046617 cites W2130429087 @default.
- W2009046617 cites W2950209042 @default.
- W2009046617 cites W2951598778 @default.
- W2009046617 cites W2953198030 @default.
- W2009046617 cites W56134234 @default.
- W2009046617 doi "https://doi.org/10.1016/s1381-1169(02)00449-1" @default.
- W2009046617 hasPublicationYear "2003" @default.
- W2009046617 type Work @default.
- W2009046617 sameAs 2009046617 @default.
- W2009046617 citedByCount "57" @default.
- W2009046617 countsByYear W20090466172012 @default.
- W2009046617 countsByYear W20090466172013 @default.
- W2009046617 countsByYear W20090466172014 @default.
- W2009046617 countsByYear W20090466172015 @default.
- W2009046617 countsByYear W20090466172016 @default.
- W2009046617 countsByYear W20090466172017 @default.
- W2009046617 countsByYear W20090466172018 @default.
- W2009046617 countsByYear W20090466172019 @default.
- W2009046617 countsByYear W20090466172020 @default.
- W2009046617 countsByYear W20090466172021 @default.
- W2009046617 countsByYear W20090466172023 @default.
- W2009046617 crossrefType "journal-article" @default.
- W2009046617 hasAuthorship W2009046617A5023363049 @default.
- W2009046617 hasAuthorship W2009046617A5031647041 @default.
- W2009046617 hasAuthorship W2009046617A5039414614 @default.
- W2009046617 hasAuthorship W2009046617A5051431915 @default.
- W2009046617 hasAuthorship W2009046617A5057055806 @default.
- W2009046617 hasAuthorship W2009046617A5081161994 @default.
- W2009046617 hasConcept C118792377 @default.
- W2009046617 hasConcept C134121241 @default.
- W2009046617 hasConcept C161790260 @default.
- W2009046617 hasConcept C178790620 @default.
- W2009046617 hasConcept C179104552 @default.
- W2009046617 hasConcept C185592680 @default.
- W2009046617 hasConcept C191897082 @default.
- W2009046617 hasConcept C192562407 @default.
- W2009046617 hasConcept C2776606100 @default.
- W2009046617 hasConcept C2778237882 @default.
- W2009046617 hasConcept C2779480358 @default.
- W2009046617 hasConcept C2780450521 @default.
- W2009046617 hasConcept C544153396 @default.
- W2009046617 hasConcept C73969872 @default.
- W2009046617 hasConceptScore W2009046617C118792377 @default.
- W2009046617 hasConceptScore W2009046617C134121241 @default.
- W2009046617 hasConceptScore W2009046617C161790260 @default.
- W2009046617 hasConceptScore W2009046617C178790620 @default.
- W2009046617 hasConceptScore W2009046617C179104552 @default.
- W2009046617 hasConceptScore W2009046617C185592680 @default.
- W2009046617 hasConceptScore W2009046617C191897082 @default.
- W2009046617 hasConceptScore W2009046617C192562407 @default.
- W2009046617 hasConceptScore W2009046617C2776606100 @default.
- W2009046617 hasConceptScore W2009046617C2778237882 @default.
- W2009046617 hasConceptScore W2009046617C2779480358 @default.
- W2009046617 hasConceptScore W2009046617C2780450521 @default.