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- W2009047024 abstract "Vanadium oxinate dissolved in such organic solvents as chloroform and nitrobenzene can be successfully used for the photometric determination of micromolar quantities of various alcohols. The sensitivity depends upon the dielectric constant of the solvent and the concentration of the reagent. Suggestions are made for using the reaction to estimate the relative reactivity of a given alcohol and the steric effect about the alcoholic OH. The reaction can also be used to differentiate alcohol isomers. Für der photometrisehen Bestimmung der Mikromolmenge verschiedener Alkoholen vorschlagt man das in solchen organischen Lösungsmittel wie Chloroform und Nitrobenzol gelöste Vanadinoxinat. Die Empfindlichkeit hängt von der Dielektrizitätskonstante des solvents und der Konzentration des Reagenses ab. Diese Reaktion gewährt eine Methode zur Abschätzung der relativen Reaktivität des gegebenen Alkohols und des sterischen Efieckts um OH des Alkohols. Die Reaktion kann auch zur Differenzierung zwischen isomeren Alkoholen verwendet werden. Pour le dosage photométrique d'une quantité micromole de divers alcools, on propose l'emploi de l'oxinate de vanadium dissous dans des solvants organiques tels que le chloroforme et le nitrobenzène. La sensibilité dépend de la constante diélectrique du solvant et de la concentration du réactif. Cette reaction donne un moyen d'évaluer la réactivité relative d'un alcool et l'effet stérique au voisinage de OH alcoolique. La réaction peut aussi être utilisée pour différencier des alcools isomères." @default.
- W2009047024 created "2016-06-24" @default.
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- W2009047024 date "1960-09-01" @default.
- W2009047024 modified "2023-09-25" @default.
- W2009047024 title "The photometric determination of alcohols by means of vanadium oxinate" @default.
- W2009047024 doi "https://doi.org/10.1016/0039-9140(60)80168-3" @default.
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