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- W2009059669 abstract "The title compounds were prepared from 1-lithio-undecafluorobicylco(2,2,1)-heptane, and from 1H,4-lithio-decafluorobicyclo(2,2,1)heptane and 1H-decafluorobicyclo(2,2,1)hept-4-yl magnesium iodide with mercuric chloride. With sulphur and caesium fluoride in dimethyl formamide, both mercurials gave the corresponding thioxides and these on hydrolysis gave the known bridgehead thiols. With sulphur alone, the undecafluoro mercurial gave mainly the disulphide and a range of polysulphides, under conditions which left the 4H-decafluoro mercurial unchanged. Conventional d.c. polarography of the mercurials indicated an inconsistency in the use of this method for determining the acidities of highly fluorinated hydrocarbons." @default.
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- W2009059669 title "Polyfluorobicyclo(2,2,1)heptanes Part VIII. Bis(undecafluorobicyclo(2,2,1)heptan-1-yl)- and bis(4H-decafluorobicyclo(2,2,1)heptan-1-yl)-mercury" @default.
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- W2009059669 doi "https://doi.org/10.1016/s0022-1139(00)81717-0" @default.
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