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- W2009061441 abstract "The local non-adiabatic dynamics near an accidental degeneracy of Σ+ = Π type in a linear triatomic system has been investigated in the context of the semiclassical approximation. An exact analytical solution of the time-dependent semiclassical equations has been found for rectilinear trajectories of the bending (π) vibrational modes. The S-matrix and transition probabilities associated with this three-state problem, which have a non-Landau-Zener character, have been defined in analytical terms. The expressions obtained for the transition probabilities may be useful in the context of the trajectory surface hopping method." @default.
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- W2009061441 date "2000-10-23" @default.
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- W2009061441 title "A semiclassical approach to the non-adiabatic dynamics problem involving three electronic states in linear triatomic systems" @default.
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- W2009061441 doi "https://doi.org/10.1088/0953-4075/33/21/323" @default.
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