Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009061773> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2009061773 endingPage "393" @default.
- W2009061773 startingPage "385" @default.
- W2009061773 abstract "We present a comprehensive study of the partially reduced polyoxomolybdate [H3-Mo57V6(NO)6O183(H2O)18]21-encapsulated in a shell of dimethyldioctadecylammonium (DODA) surfacmolecules. Treatment of an aqueous solution of (NH4)21[H3Mo57V6-(NO)6O183(H2O)18] . 65H2O (1a) with a trichloromethane solution of the surfactant leads to instant transfer of the encapsulated complex anion into the organic phase. Results from vibrational spectroscopy. analytical ultracentrifugation, small-angle X-ray scattering, transmission electron microscopy, elemental analysis, and Langmuir compression isotherms are consistent with a single polyoxometalate core encapsulated within a shell of 20 DODA molecules. The molar mass of the supramolecular assembly is 20249 gmol(-1) and the diameter is 3.5 nm. A material with the empirical formula (DODA)20(NH4)[H3-Mo57V6NO)6O183(H2O)18] (2) was isolated as a dark violet solid, which readily dissolves in organic solvents. Slow evaporation of solutions of 2 on solid substrates forces the hydrophobic particles to aggregate into a cubic lattice. Annealing these so-formed films at elevated temperature causes de-wetting with terrace formation similar to liquid crystals and block copolymers. Compound 2 forms a stable Langmuir monolayer at the air-water interface; Langmuir-Blodgett multilayers are readily prepared by repeated transfer of monolayers on solid substrates. The films were characterized by optical ellipsometry, Brewster angle microscopy, transmission electron microscopy, and X-ray reflectance." @default.
- W2009061773 created "2016-06-24" @default.
- W2009061773 creator A5002800063 @default.
- W2009061773 creator A5015586580 @default.
- W2009061773 creator A5020049917 @default.
- W2009061773 creator A5045582390 @default.
- W2009061773 creator A5066573214 @default.
- W2009061773 creator A5070894297 @default.
- W2009061773 creator A5091881096 @default.
- W2009061773 date "2000-01-17" @default.
- W2009061773 modified "2023-10-16" @default.
- W2009061773 title "Surfactant-Encapsulated Clusters (SECs): (DODA)20(NH4)[H3Mo57V6(NO)6O183(H2O)18], a Case Study" @default.
- W2009061773 doi "https://doi.org/10.1002/(sici)1521-3765(20000117)6:2<385::aid-chem385>3.0.co;2-a" @default.
- W2009061773 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11931120" @default.
- W2009061773 hasPublicationYear "2000" @default.
- W2009061773 type Work @default.
- W2009061773 sameAs 2009061773 @default.
- W2009061773 citedByCount "227" @default.
- W2009061773 countsByYear W20090617732012 @default.
- W2009061773 countsByYear W20090617732013 @default.
- W2009061773 countsByYear W20090617732014 @default.
- W2009061773 countsByYear W20090617732015 @default.
- W2009061773 countsByYear W20090617732016 @default.
- W2009061773 countsByYear W20090617732017 @default.
- W2009061773 countsByYear W20090617732018 @default.
- W2009061773 countsByYear W20090617732019 @default.
- W2009061773 countsByYear W20090617732020 @default.
- W2009061773 countsByYear W20090617732021 @default.
- W2009061773 countsByYear W20090617732022 @default.
- W2009061773 countsByYear W20090617732023 @default.
- W2009061773 crossrefType "journal-article" @default.
- W2009061773 hasAuthorship W2009061773A5002800063 @default.
- W2009061773 hasAuthorship W2009061773A5015586580 @default.
- W2009061773 hasAuthorship W2009061773A5020049917 @default.
- W2009061773 hasAuthorship W2009061773A5045582390 @default.
- W2009061773 hasAuthorship W2009061773A5066573214 @default.
- W2009061773 hasAuthorship W2009061773A5070894297 @default.
- W2009061773 hasAuthorship W2009061773A5091881096 @default.
- W2009061773 hasBestOaLocation W20090617732 @default.
- W2009061773 hasConcept C113196181 @default.
- W2009061773 hasConcept C115958267 @default.
- W2009061773 hasConcept C120665830 @default.
- W2009061773 hasConcept C121332964 @default.
- W2009061773 hasConcept C146088050 @default.
- W2009061773 hasConcept C147789679 @default.
- W2009061773 hasConcept C171250308 @default.
- W2009061773 hasConcept C178790620 @default.
- W2009061773 hasConcept C184651966 @default.
- W2009061773 hasConcept C185592680 @default.
- W2009061773 hasConcept C192562407 @default.
- W2009061773 hasConcept C2780048723 @default.
- W2009061773 hasConcept C35068176 @default.
- W2009061773 hasConcept C55493867 @default.
- W2009061773 hasConcept C7070889 @default.
- W2009061773 hasConcept C8010536 @default.
- W2009061773 hasConceptScore W2009061773C113196181 @default.
- W2009061773 hasConceptScore W2009061773C115958267 @default.
- W2009061773 hasConceptScore W2009061773C120665830 @default.
- W2009061773 hasConceptScore W2009061773C121332964 @default.
- W2009061773 hasConceptScore W2009061773C146088050 @default.
- W2009061773 hasConceptScore W2009061773C147789679 @default.
- W2009061773 hasConceptScore W2009061773C171250308 @default.
- W2009061773 hasConceptScore W2009061773C178790620 @default.
- W2009061773 hasConceptScore W2009061773C184651966 @default.
- W2009061773 hasConceptScore W2009061773C185592680 @default.
- W2009061773 hasConceptScore W2009061773C192562407 @default.
- W2009061773 hasConceptScore W2009061773C2780048723 @default.
- W2009061773 hasConceptScore W2009061773C35068176 @default.
- W2009061773 hasConceptScore W2009061773C55493867 @default.
- W2009061773 hasConceptScore W2009061773C7070889 @default.
- W2009061773 hasConceptScore W2009061773C8010536 @default.
- W2009061773 hasIssue "2" @default.
- W2009061773 hasLocation W20090617731 @default.
- W2009061773 hasLocation W20090617732 @default.
- W2009061773 hasLocation W20090617733 @default.
- W2009061773 hasLocation W20090617734 @default.
- W2009061773 hasOpenAccess W2009061773 @default.
- W2009061773 hasPrimaryLocation W20090617731 @default.
- W2009061773 hasRelatedWork W1546802802 @default.
- W2009061773 hasRelatedWork W1963799578 @default.
- W2009061773 hasRelatedWork W1977957253 @default.
- W2009061773 hasRelatedWork W2044261051 @default.
- W2009061773 hasRelatedWork W2057098840 @default.
- W2009061773 hasRelatedWork W2061393953 @default.
- W2009061773 hasRelatedWork W2087464785 @default.
- W2009061773 hasRelatedWork W2313857538 @default.
- W2009061773 hasRelatedWork W2376711334 @default.
- W2009061773 hasRelatedWork W2995415174 @default.
- W2009061773 hasVolume "6" @default.
- W2009061773 isParatext "false" @default.
- W2009061773 isRetracted "false" @default.
- W2009061773 magId "2009061773" @default.
- W2009061773 workType "article" @default.