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• W2009095725 startingPage "8282" @default.
• W2009095725 abstract "The 90K solid-state structures, room temperature absorption, and room temperature and 17 K emission spectra of seven different salts of [Cu(I)(bfp)2]+ (bfp = 2,9-bis(trifluoromethyl)-1,10-phenanthroline) have been determined. To quantify the distortion of the Cu coordination environment, a distortion parameter ζ is defined that is a combined measure of the flattening, rocking, and wagging distortions of the complex cations. In general, the distortion in the (bfp) cations is less than found previously for Cu(I)(dmp)2 (dmp = 2,9-dimethyl-1,10-phenanthroline) salts, in particular the flattening is reduced because of the bulkier 2,9-substituents. The 17 K lifetimes range up to 1.8 μs in the series of solids examined and, with the marked exception of the BF4- salt, correlate linearly with the distortion parameter ζ. The emission wavelength red-shifts with decreasing lifetime, which implies that an increased ground-state distortion is associated with a smaller energy gap." @default.
• W2009095725 created "2016-06-24" @default.
• W2009095725 creator A5010950609 @default.
• W2009095725 creator A5084865051 @default.
• W2009095725 creator A5089578194 @default.
• W2009095725 date "2004-11-23" @default.
• W2009095725 modified "2023-09-24" @default.
• W2009095725 title "Cu^(I)(2,9-Bis(trifluoromethyl)-1,10-phenanthroline)₂⁺ Complexes: Correlation between Solid-State Structure and Photoluminescent Properties" @default.
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• W2009095725 doi "https://doi.org/10.1021/ic049638s" @default.
• W2009095725 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15606174" @default.
• W2009095725 hasPublicationYear "2004" @default.
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