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- W2009146522 abstract "Polyacrylamide (pacr) gels have attractive properties that are the basis for several important applications in bioanalytical chemistry. For example, they provide a hydrophilic environment with a controllable pore size that allows for the entrapment and immobilization of biopolymers in their active forms. Pacr gels have long been used as matrices for gel electrophoresis and gel permeation chromatography. Recently, they described the construction of an enzyme electrode, based on the ideas of Hill and co-workers, that consisted of an enzyme/mediator system entrapped in a pacr interface between a carbon support bed and the solution. These pacr-modified electrodes mediated the direct and specific amperometric oxidation of glucose. Others have studied pacr-modified electrodes, and a variety of applications based on the electrochemically driven swelling of polyelectrolyte gels can be envisioned. Thus these electrodes show promise as permeable, multicomponent interfaces between an electrode substrate and solution. The purpose of the work described here was 3-fold: first, to study charge transport through the ferrocene/graphite/pacr gel composite; second, to document preliminary investigations of the photoactivation process occurring in the ferrocene/TiO/sub 2//pacr gel; and third, to examine the analytical utility of the pacr electrode." @default.
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- W2009146522 date "1986-11-01" @default.
- W2009146522 modified "2023-09-24" @default.
- W2009146522 title "Polyacrylamide/graphite and polyacrylamide/titanium dioxide gel electrodes" @default.
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- W2009146522 doi "https://doi.org/10.1021/ac00126a064" @default.
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