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- W2009166095 abstract "Abstract It was observed that the variance of the solute retention time with the mobile phase composition in ternary reversed-phase high-performance liquid chromatography (RP-HPLC) approximately obeys a simple exponential model that is involved in the Snyder solvent strength theory. Using Newton or Marquardt algorthms, the values of the unknown non-linear parameters in the model were obtained, and further used to predict the retention time of solute as a function of ternary solvent composition to a good approximation, based upon three isocratic HPLC runs only. No dead time is needed for the prediction here. To test the model further, four sets of experimental data published by other groups were used. Three of the sets of experimental data conformed well with this model, but the other set showed serious deviations. In the latter instance, however, all the mobile phases used contained 5 m M heptanesulphonate and 1% acetic acid in addition to methanol, acetonitrile and water. For practical use, some problems in the non-linear least-squares estimation are discussed." @default.
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- W2009166095 date "1991-08-01" @default.
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- W2009166095 title "Experimental modell for predicting solute retention time as a function of mobile phase composition in ternary reversed-phase high-performance liquid chromatography" @default.
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- W2009166095 doi "https://doi.org/10.1016/s0021-9673(01)87165-x" @default.
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