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• W2009172955 abstract "The reaction of Cp2Ti(η2-Me3SiC2SiMe3) with equimolar amounts of PhCɢC-CɢCPh gives the unstable five-membered titanacyclocumulene 1, which is stabilized by dimerization to yield the dinuclear complex 2. In this reaction complex 1 shows an equilibrium and also behaves as a metallacyclocumulene and a metal alkyne complex. By the coupling of the internal double bond of the cyclocumulene with a complexed triple bond of the diyne, a complex with fused titanacyclopentadiene and titanacyclopentene is formed. With acetone and water complex 1 reacts like an alkyne complex to give the titanadihydrofuran 4 and the titanoxane 5. Complex 2 was investigated by an X-ray structural determination." @default.
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• W2009172955 date "1997-05-01" @default.
• W2009172955 modified "2023-10-14" @default.
• W2009172955 title "Reactions of the phenyl-substituted five-membered titanacyclocumulene ȁ Unusual coupling of a 1,4-disubstituted 1,3-butadiyne with two titanium atoms" @default.
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• W2009172955 doi "https://doi.org/10.1016/s0022-328x(96)06694-6" @default.
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