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- W2009173251 abstract "The conformations of the (1→4)-linked α-d-galacturono-di- (1) and -tri-saccharide (2) in aqueous solutions have been analysed by n.m.r. spectroscopy and MM2CARB calculations. The 3JC,H and n.O.e. values did not change with temperature and were comparable for 1 and 2. Four energy regions were found on the relaxed (π, φ) map for 1 computed by the MM2CARB method. Theoretical n.O.e. values, based on the geometry and the abundance of the most populated conformer, accorded with experimental values. The magnitudes of πH φH for the glycosidic bond suggest that a right-handed three-fold helical arrangement can be formed by pectic acid oligosaccharides in solution." @default.
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- W2009173251 title "Conformations of (1→4)-linked α-d-galacturono-di- and -tri-saccharides in solution analysed by n.m.r. measurements and theoretical calculations" @default.
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- W2009173251 doi "https://doi.org/10.1016/0008-6215(91)80003-6" @default.
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