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• W2009179670 abstract "[reaction: see text]. Rate constants for hydrogen abstraction from phenols by a prefluorescent-TEMPO probe are reported. The nitroxide is employed as a potential model of peroxyl radicals. The probe works by nitroxide suppression of the fluorescence of the chromophore. The fluorescence is restored when the nitroxide abstracts a hydrogen atom to produce the diamagnetic hydroxylamine. The phenols studied in this project exhibited rate constants between 0.003 and 0.2 M(-1) s(-1). A deuterium isotope effect of 10 for TROLOX confirms that the mechanism is dominated by hydrogen transfer." @default.
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• W2009179670 date "2003-10-01" @default.
• W2009179670 modified "2023-09-25" @default.
• W2009179670 title "A New Method to Study Antioxidant Capability: Hydrogen Transfer from Phenols to a Prefluorescent Nitroxide" @default.
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• W2009179670 doi "https://doi.org/10.1021/ol035589w" @default.
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