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• W2009203148 abstract "Novel periodic mesostructured organometallic silicas of MCM-41 type bearing homogeneously distributed bis(8-quinolinolato)dioxomolybdenum(VI) inside the channel walls (denoted as MoO2Q2@PMO-x) are synthesized via a convenient one-pot method and examined as catalysts in the epoxidation of cyclooctene. The ordered mesoporous structures as well as the organometallic groups incorporated into the framework are fully determined by comprehensive characterization techniques such as XRD, TEM, N2 adsorption/desorption, SEM, FT-IR, UV–vis spectroscopy, solid-state NMR, ICP-AES, XPS and TG/DSC. MoO2Q2@PMO-6% catalyst exhibits higher activity for the epoxidation of cyclooctene with tert-butyl hydroperoxide than other MoO2Q2@PMO materials and its homogeneous or randomly grafted analogue." @default.
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• W2009203148 date "2011-10-01" @default.
• W2009203148 modified "2023-10-18" @default.
• W2009203148 title "Periodic mesoporous organosilicas with bis(8-quinolinolato) dioxomolybdenum(VI) inside the channel walls" @default.
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• W2009203148 doi "https://doi.org/10.1016/j.jcis.2011.06.008" @default.
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