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- W2009217686 abstract "The electrode reaction of the Eu(III)—Eu(II) system on the mercury electrode in waterAN and waterDMSO mixtures has been studied. Charge transfer rate constants, and formal potentials at different mixed solvent compositions are determined. The standard rate constants of the process investigated passed through a minimum, as the concentration of AN in waterAN mixtures increased, while in waterDMSO mixtures it increased with increasing DMSO content. Formal potentials expressed in the ferrocene scale were used to calculate the difference between Gibbs free energies of transfer of the Eu(III) and Eu(II) ions from water to waterAN and waterDMSO mixtures." @default.
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- W2009217686 date "1988-01-01" @default.
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- W2009217686 title "Electrode kinetics of the Eu(III)—Eu(II) system at mercury electrodes in wateracetonitrile (AN) and waterDMSO mixtures" @default.
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- W2009217686 doi "https://doi.org/10.1016/0013-4686(88)80025-2" @default.
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