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- W2009238439 abstract "A newly prepared ligand, N,N-bis(pyrazol-1-ylmethyl)benzylamine (L) reacted with metal ions to form [FeLCl3], [NiL(NCS)2(MeOH)], [MLX2](M = CoII, CuII or ZnII, X = Cl–, Br– or NCS–) and [(CuLI)2]. The crystallographically determined structures of [CoLCl2] and [CoL(NCS)2] reveal the co-ordination sphere of cobalt(II) to be intermediate between distorted tetrahedral and trigonal bipyramidal. In [NiL(NCS)2(MeOH)] the co-ordination sphere of nickel(II) ion is distorted octahedral while that of copper(II) in [CuLCl2] is distorted square pyramidal. The complex [(CuLI)2] displays distorted tetrahedral geometry around copper(I), and [ZnLBr2] shows distorted tetrahedral geometry around zinc(II)." @default.
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- W2009238439 date "1995-01-01" @default.
- W2009238439 modified "2023-09-23" @default.
- W2009238439 title "Synthesis, properties and molecular structures of iron(III), cobalt(II), nickel(II), copper(II), copper(I) and zinc(II) complexes with N,N-bis(pyrazol-1-ylmethyl)benzylamine" @default.
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- W2009238439 doi "https://doi.org/10.1039/dt9950003503" @default.
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