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- W2009297718 abstract "Heterogeneous zirconocene catalysts were prepared with an unconventional method by grafting mesoporous silica SBA-15 fiber with ZrCl4 in gas or liquid phase and subsequently with lithium salt of cyclopentadiene (Cp) or indene (Ind). In order to obtain a better understanding of the bonding modes of the zirconium and the ligands, the ZrClx/SiO2 and ZrClxL/SiO2 were now for the first time characterized by several techniques, including elemental analysis, FTIR spectroscopy, 1H MAS NMR and 13C CP MAS NMR. The results verify the η5-bonding of the ligands to the metal center, which in turn was discovered to be both mono- and bifunctionally bonded to the silica. The catalysts were tested in ethylene polymerization, in which they yielded polyethylene with moderate activities." @default.
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- W2009297718 date "2007-02-01" @default.
- W2009297718 modified "2023-09-26" @default.
- W2009297718 title "Characterization of stepwise prepared, silica supported zirconocene catalysts designed for olefin polymerization" @default.
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- W2009297718 doi "https://doi.org/10.1016/j.molcata.2006.07.072" @default.
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