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• W2009301688 abstract "Emerging photovoltaic devices based on molecular and nanomaterials are mostly excitonic in nature. The initial absorption of a photon in these materials creates an exciton that can subsequently dissociate in each material or at their interfaces to give charge carriers. Any attempt at mechanistic understanding of excitonic solar cells must start with drawing energy level diagrams. This seemingly elementary exercise, which is described in textbooks for inorganic solar cells, has turned out to be a difficult subject in the literature. The problem stems from conceptual confusion of single-particle energy with quasi-particle energy and the misleading practice of mixing the two on the same energy level diagram. Here, I discuss how to draw physically accurate energy diagrams in excitonic solar cells using only single-particle energies (ionization potentials and electron affinities) of both ground and optically excited states. I will briefly discuss current understanding on the electronic energy landscape responsible for efficient charge separation in excitonic solar cells." @default.
• W2009301688 created "2016-06-24" @default.
• W2009301688 creator A5085318525 @default.
• W2009301688 date "2014-06-17" @default.
• W2009301688 modified "2023-09-30" @default.
• W2009301688 title "How to Draw Energy Level Diagrams in Excitonic Solar Cells" @default.
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• W2009301688 doi "https://doi.org/10.1021/jz5008438" @default.
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