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• W2009334343 abstract "Abstract Poly( N ‐vinyl‐γ‐sodium aminobutyrate‐ co ‐sodium acrylate) (VSA–SA)/polysulfone (PS) composite membranes were prepared for the separation of CO 2 . VSA–SA contained secondary amines and carboxylate ions that could act as carriers for CO 2 . At 20°C and 1.06 atm of feed pressure, a VSA–SA/PS composite membrane displayed a pure CO 2 permeation rate of 6.12 × 10 −6 cm 3 (STP)/cm 2 s cmHg and a CO 2 /CH 4 ideal selectivity of 524.5. In experiments with a mixed gas of 50 vol % CO 2 and 50 vol % CH 4 , at 20°C and 1.04 atm of feed pressure, the CO 2 permeation rate was 9.2 × 10 −6 cm 3 (STP)/cm 2 s cmHg, and the selectivity of CO 2 /CH 4 was 46.8. Crosslinkages with metal ions were effective for increasing the selectivity. Both the selectivity of CO 2 over CH 4 and the CO 2 permeation rate had a maximum against the carrier concentration. The high CO 2 permeation rate originated from the facilitated transport mechanism, which was confirmed by Fourier transform infrared with attenuated total reflectance techniques. The performance of the membranes prepared in this work had good stability. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 275–282, 2006" @default.
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• W2009334343 date "2006-01-26" @default.
• W2009334343 modified "2023-10-18" @default.
• W2009334343 title "CO2-facilitated transport through poly(N-vinyl-γ-sodium aminobutyrate-co-sodium acrylate)/polysulfone composite membranes" @default.
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• W2009334343 doi "https://doi.org/10.1002/app.23100" @default.
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