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- W2009348097 abstract "The reaction of Ph 2 Si(NHNHMe) 2 (1) with MeI results in a mixture of two six-membered ring isomers, 1,2,4,5-tetraaza-1,4-dimethyl-3,3,6,6-tetraphenyl-3,6-disilacyclohexane (2), 45%, and 1,2,4,5-tetraaza-1,5-dimethyl-3,3,6,6-tetraphenyl-3,6-disilacyclohexane (3), 40%. The reaction of 1 with HCl or Ph 2 SiCl 2 proceeds in a similar fashion. The thermolysis of 1 is studied from 25–600 °C. In the range of 250–300 °C, about 50% of 1 is converted into 2,3, and 1,2,4-triaza-1-methyl-4-methylamino-3,3,5,5-tetraphenyl-3,5-disilacyclopentane, 8. Possible pathways for the formation of 2,3, and 8 in these cyclization reactions are discussed." @default.
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- W2009348097 date "1994-08-01" @default.
- W2009348097 modified "2023-10-18" @default.
- W2009348097 title "Cyclization of Ph2Si(NHNHMe)2. II. Reactions with methyl iodide, HCl, and Ph2SiCl2, and thermolysis" @default.
- W2009348097 cites W3145759963 @default.
- W2009348097 doi "https://doi.org/10.1139/v94-222" @default.
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