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- W2009367500 abstract "1H NMR spectra of biotin and four related hexahydrothienoimidazolones in which the endo pentanoate side chain of biotin is replaced by another endo or exo substituent, and the urea nitrogen atoms are substituted with benzyl groups, have been obtained at 300 MHz. Vicinal coupling constants differentiate cis and trans proton pairs. The generalized Karplus equation was utilized to calculate dihedral angles from vicinal proton-proton coupling constants. The conformation of biotin in solution, calculated from coupling constants, is in good agreement with solid state X-ray crystallographic data." @default.
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- W2009367500 date "1985-01-01" @default.
- W2009367500 modified "2023-10-18" @default.
- W2009367500 title "300 Mhz 1H NMR spectra and conformations of biotin and related hexahydrothienoimidazolone derivatives" @default.
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- W2009367500 doi "https://doi.org/10.1016/s0040-4020(01)96626-8" @default.
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