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- W2009382598 abstract "Abstract Crystal-field splittings of Ho 3+ ions in HoCl 3 ·6H 2 O are re-analyzed in order to obtain a consistent and standardized crystal-field parameter (CFP) set. Experimental energy levels were fitted to Hamiltonian parameters representing the combined free-ion and crystal-field interactions for a 4f 10 ion in the actual C 2 symmetry site. A relatively low r.m.s. deviation of 8.8 cm −1 is achieved. The reliable starting values of the CFPs were obtained from superposition model analysis. The crystal-field strength, S , is significantly larger for HoCl 3 ·6H 2 O ( S = 262 cm −1 ) than for Ho 3+ :LaCl 3 ( S = 133 cm −1 ) or Ho(C 2 H 5 SO 4 ) 3 ·9H 2 O ( S = 183 cm −1 ), in which Ho 3+ ion is coordinated by nine chlorine atoms or nine oxygen atoms from water molecules, respectively." @default.
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- W2009382598 date "2008-02-01" @default.
- W2009382598 modified "2023-09-27" @default.
- W2009382598 title "Crystal-field analysis of Ho3+ ions in HoCl3·6H2O" @default.
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- W2009382598 doi "https://doi.org/10.1016/j.jallcom.2007.04.091" @default.
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