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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009386543> ?p ?o ?g. }

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• W2009386543 abstract "Transient stimulated emission has been measured by applying the pump-and-probe technique to a series of substituted oligothiophenes in solution. The observed dynamics are assigned to the intraband population relaxation associated with the internal energy redistribution process. This leads ultimately to a molecular conformation more quinoid in character and almost planar. Two characteristic time constants are obtained: the first, about 500–800 fs, is assigned to vibrational relaxation while the second, about 4 ps, is assigned to torsional relaxation, which involves inter-ring torsional activity. We estimate average dissipation times of ca. 170 and ca. 600 fs for vibrational and torsional quanta, respectively." @default.
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• W2009386543 date "1996-03-01" @default.
• W2009386543 modified "2023-09-28" @default.
• W2009386543 title "Femtosecond vibrational and torsional energy redistribution in photoexcited oligothiophenes" @default.
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• W2009386543 doi "https://doi.org/10.1016/0009-2614(96)00107-8" @default.
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