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• W2009391421 abstract "A δ-MgCl2 was synthesized by reacting metallic magnesium with 1-chlorobutane. This salt is extremely anhydrous and shows a high crystallographic disorder and reactivity toward Lewis bases. By using this δ-MgCl2, eight poly(ethylene glycol)/(δ-MgCl2)x complexes, with 3.29×10−3≤x≤ 7.00×10−1, were synthetized. The interaction between Mg2+ ion and poly(ethylene glycol) (PEG) ligands was investigated by mid and far FT-IR spectroscopy. It was concluded that in these polymer electrolytes: (a) Mg2+ ions could be accommodated in two distinct distributions of coordination sites and (b) PEG chains present a TGT conformation. Conductivity data of PEG 400/(δ-MgCl2)x was determined by impedance spectroscopy. The room temperature conductivities of these polymer electrolytes are ca. 1.9×10−5 S cm−1." @default.
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• W2009391421 date "1998-04-01" @default.
• W2009391421 modified "2023-10-09" @default.
• W2009391421 title "A novel electrolytic complex based on δ-MgCl2 and poly(ethylene glycol) 400" @default.
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• W2009391421 doi "https://doi.org/10.1016/s0013-4686(97)10023-8" @default.
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