Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009422405> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2009422405 endingPage "3723" @default.
- W2009422405 startingPage "3716" @default.
- W2009422405 abstract "The ν2 (bending) fundamental band of CH2 in its X̃ 3B1 ground electronic state has been studied using tunable diode laser spectroscopy and also the LMR (laser magnetic resonance) technique in the 800–911 cm−1 and 1030–1173 cm−1 regions. For the diode laser study, a multiple-traversal absorption cell was used with Zeeman modulation, and the CH2 radicals were produced by a mild discharge in a flowing mixture of ketene (∼0.3 Torr) and helium (∼2 Torr). Under these conditions, the apparent lifetime of CH2 following cutoff of the discharge was about 1 ms. A total of 53 new transitions with rotational quantum numbers up to N=10, K″a =3, and Ka =2 were observed to add to the 11 transitions previously measured in this band. A combined analysis of the present data and all the previous pure rotational and ν2 band results on CH2 has yielded an improved set of molecular parameters, including the first determination of centrifugal distortion effects for the dominant spin–spin interaction parameter, D. The present data have also been used in a comprehensive new analysis of triplet methylene rotation–vibration energies using the nonrigid bender Hamiltonian by Bunker et al. in an accompanying paper." @default.
- W2009422405 created "2016-06-24" @default.
- W2009422405 creator A5021348426 @default.
- W2009422405 creator A5082845016 @default.
- W2009422405 date "1986-10-01" @default.
- W2009422405 modified "2023-10-02" @default.
- W2009422405 title "The ν2 fundamental band of triplet CH2" @default.
- W2009422405 cites W1965662560 @default.
- W2009422405 cites W1976054884 @default.
- W2009422405 cites W1976669464 @default.
- W2009422405 cites W1980419873 @default.
- W2009422405 cites W1982976316 @default.
- W2009422405 cites W1991544635 @default.
- W2009422405 cites W1994084283 @default.
- W2009422405 cites W2002001887 @default.
- W2009422405 cites W2023546864 @default.
- W2009422405 cites W2026750696 @default.
- W2009422405 cites W2041032196 @default.
- W2009422405 cites W2045900348 @default.
- W2009422405 cites W2052425348 @default.
- W2009422405 cites W2054813015 @default.
- W2009422405 cites W2072059498 @default.
- W2009422405 cites W2078750907 @default.
- W2009422405 cites W2081430360 @default.
- W2009422405 cites W2090922367 @default.
- W2009422405 cites W2093922597 @default.
- W2009422405 cites W2104793791 @default.
- W2009422405 cites W2143085463 @default.
- W2009422405 cites W2160106826 @default.
- W2009422405 cites W255638313 @default.
- W2009422405 cites W2600484655 @default.
- W2009422405 doi "https://doi.org/10.1063/1.450943" @default.
- W2009422405 hasPublicationYear "1986" @default.
- W2009422405 type Work @default.
- W2009422405 sameAs 2009422405 @default.
- W2009422405 citedByCount "65" @default.
- W2009422405 countsByYear W20094224052018 @default.
- W2009422405 countsByYear W20094224052020 @default.
- W2009422405 countsByYear W20094224052021 @default.
- W2009422405 countsByYear W20094224052022 @default.
- W2009422405 countsByYear W20094224052023 @default.
- W2009422405 crossrefType "journal-article" @default.
- W2009422405 hasAuthorship W2009422405A5021348426 @default.
- W2009422405 hasAuthorship W2009422405A5082845016 @default.
- W2009422405 hasConcept C113196181 @default.
- W2009422405 hasConcept C115260700 @default.
- W2009422405 hasConcept C120665830 @default.
- W2009422405 hasConcept C121332964 @default.
- W2009422405 hasConcept C167812310 @default.
- W2009422405 hasConcept C181500209 @default.
- W2009422405 hasConcept C184779094 @default.
- W2009422405 hasConcept C185592680 @default.
- W2009422405 hasConcept C25227350 @default.
- W2009422405 hasConcept C43617362 @default.
- W2009422405 hasConcept C520434653 @default.
- W2009422405 hasConcept C62520636 @default.
- W2009422405 hasConcept C69523127 @default.
- W2009422405 hasConceptScore W2009422405C113196181 @default.
- W2009422405 hasConceptScore W2009422405C115260700 @default.
- W2009422405 hasConceptScore W2009422405C120665830 @default.
- W2009422405 hasConceptScore W2009422405C121332964 @default.
- W2009422405 hasConceptScore W2009422405C167812310 @default.
- W2009422405 hasConceptScore W2009422405C181500209 @default.
- W2009422405 hasConceptScore W2009422405C184779094 @default.
- W2009422405 hasConceptScore W2009422405C185592680 @default.
- W2009422405 hasConceptScore W2009422405C25227350 @default.
- W2009422405 hasConceptScore W2009422405C43617362 @default.
- W2009422405 hasConceptScore W2009422405C520434653 @default.
- W2009422405 hasConceptScore W2009422405C62520636 @default.
- W2009422405 hasConceptScore W2009422405C69523127 @default.
- W2009422405 hasIssue "7" @default.
- W2009422405 hasLocation W20094224051 @default.
- W2009422405 hasOpenAccess W2009422405 @default.
- W2009422405 hasPrimaryLocation W20094224051 @default.
- W2009422405 hasRelatedWork W1017473139 @default.
- W2009422405 hasRelatedWork W113322465 @default.
- W2009422405 hasRelatedWork W1965026117 @default.
- W2009422405 hasRelatedWork W1995792991 @default.
- W2009422405 hasRelatedWork W2009624935 @default.
- W2009422405 hasRelatedWork W2042595795 @default.
- W2009422405 hasRelatedWork W2076912795 @default.
- W2009422405 hasRelatedWork W2572054017 @default.
- W2009422405 hasRelatedWork W2952819425 @default.
- W2009422405 hasRelatedWork W3098769584 @default.
- W2009422405 hasVolume "85" @default.
- W2009422405 isParatext "false" @default.
- W2009422405 isRetracted "false" @default.
- W2009422405 magId "2009422405" @default.
- W2009422405 workType "article" @default.