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- W2009473313 abstract "Through the theoretical study of concentration-dependent thermodynamic and microscopic functions in some reports, chemical short-range orders (CSROs) have been proved to persist in Cu–Sn melts. However, it is not clear insofar in which concentration and temperature ranges do these CSROs exist in melts, and how they change with temperature. This study investigates the liquid structure with temperature of Cu–Sn alloys by electrical resistivity and DSC. The results show that some CSROs inheriting solid structures bring abnormal transition of resistivity at a temperature hundreds of degrees above the liquidus for all the studied Cu–Sn melt. Especially for the melts with 50 to 70% Cu, there also exist ‘associates’ of unlike atoms, which reduce continuously with increasing temperature after melting and result in negative temperature coefficients of resistivities (TCRs). In the figures of DSC-temperature, some endothermic peaks consistent with the temperatures of resistivity transitions verify these abnormal transitions of liquid structure." @default.
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- W2009473313 date "2006-10-01" @default.
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- W2009473313 title "Effects of compound formation on liquid structure in Cu–Sn melts as a function of temperature" @default.
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- W2009473313 doi "https://doi.org/10.1080/00319100600757458" @default.
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